Polyurethane foam :
While not the most abundant of insulations, polyurethane foams are an excellent form of insulation. Nowadays, polyurethane foams use non-chlorofluorocarbon (CFC) gas for use as a blowing agent. This helps to decrease the amount of damage to the ozone layer. They are relatively light, weighing approximately two pounds per cubic foot (2 lb/ft^3). They have an R-value of approximately R-6.3 per inch of thickness. There are also low density foams that can be sprayed into areas that have no insulation. These types of polyurethane insulation tend to have approximately R-3.6 rating per inch of thickness. Another advantage of this type of insulation is that it is fire resistant.
Polystyrene is a waterproof thermoplastic foam which is an excellent sound and temperature insulation material. It comes in two types, expanded (EPS) and extruded (XEPS) also known as Styrofoam. The two types differ in performance ratings and cost. The more costly XEPS has a R-value of R-5.5 while EPS is R-4. Polystyrene insulation has a uniquely smooth surface which no other type of insulation possesses.
Typically the foam is created or cut into blocks, ideal for wall insulation. The foam is flammable and needs to be coated in a fireproofing chemical called Hexabromocyclododecane (HBCD). HBCD has been brought under fire recently for health and environmental risks associated with its use.